Qiss

The relational approach to quantum states asserts that the physical description of quantum systems is always relative to something or someone. In relational quantum mechanics (RQM) it is relative to other quantum systems, in the (neo-)Copenhagen interpretation of quantum theory to measurement contexts, and in QBism to the beliefs of the agents. In contrast to the other two interpretations, in RQM any interaction between two quantum systems counts as a “measurement”, and the terms “observer” and “observed system” apply to arbitrary systems. We show, in the form of a no-go theorem, that in RQM the physical description of a system relative to an observer cannot represent knowledge about the observer in the conventional sense of this term. The problem lies in the ambiguity in the choice of the basis with respect to which the relative states are to be defined in RQM. In interpretations of quantum theory where observations play a fundamental role, the problem does not arise because the experimental context defines a preferred basis.

The study of thermodynamic fluctuations allows one to relate the free energy difference between two equilibrium states with the work done on a system through processes far from equilibrium. This finding plays a crucial role in the quantum regime, where the definition of work becomes non-trivial. Based on these relations, here we develop a simple interfeQILab Rometric method allowing a direct estimation of the work distribution and the average dissipative work during a driven thermodynamic process by superposing the forward and time-reversal evolutions of the process. We show that our scheme provides useful upper bounds on the average dissipative work even without full control over the thermodynamic process, and we propose methodological variations depending on the possible experimental limitations encountered. Finally, we exemplify its applicability by an experimental proposal for implementing our method on a quantum photonics system, on which the thermodynamic process is performed through polarization rotations induced by liquid crystals acting in a discrete temporal regime.